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Base promoted peroxide systems for the efficient synthesis of nitroarenes and benzamides
Authors:Sampa Gupta  Alisha Ansari  Koneni V Sashidhara
Institution:1. Medicinal and Process Chemistry Division, CSIR-Central Drug Research Institute, Sector 10, Jankipuram Extension, Sitapur Road, Lucknow 226031, India;2. Academy of Scientific and Innovative Research, New Delhi 110025, India
Abstract:A useful and efficient approach for the synthesis of nitroarenes from several aromatic amines (including heterocycles) using peroxide and base has been developed. This oxidative reaction is very easy to handle and afforded the products in good yields. Formation of benzamides from benzylamine was also successfully carried out with this metal-free catalytic system in good to excellent yields.
Keywords:Corresponding author at: Medicinal and Process Chemistry Division  CSIR-Central Drug Research Institute  Sector 10  Jankipuram Extension  Sitapur Road  Lucknow 226031  India    Aniline  Nitrobenzene  Benzyl amine  Benzamide  Oxidation  Base  Peroxide
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