首页 | 本学科首页   官方微博 | 高级检索  
     


1,4-Phenylene-bis-((1-methyl-1H-pyrazol-5-yl)borinic 8-oxyquinolinate) as a photoredox catalyst in the atom transfer radical addition of iodoperfluoroalkanes to alkenyl groups bearing organoboron compounds
Authors:Marcin Kublicki  Błażej Ogonowski  Dariusz Wieczorkowski  Krzysztof Durka  Tomasz Kliś
Affiliation:Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
Abstract:The key photocatalytic properties of a transition-metal-free heteroleptic complex derived from 1,4-phenyldiboronic acid were evaluated. This compound was utilized in the atom transfer radical addition of iodoperfluoroalkanes to a series of alkenyl group bearing organoboron compounds. The products of these reactions retained the B />C bond, and Suzuki-Miyaura coupling of one product gave biphenyl derivatives. The X-ray analysis of one of the obtained perfluoroalkylated boronic acids revealed the presence of open star-shaped channels.</td>
		  </tr> 
		  <tr>
		   <td align=
Keywords:Corresponding author.  Photoredox catalysis  Perfluoroalkanes  Organoboranes  Quinoline
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号