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A concise synthesis of (+)-goniofufurone, (+)-7-epi-goniofufurone, (+)-crassalactones B and C
Authors:Yanli Zhang  Xiaojing Liu  Feng Shui  Faling Zhou  Jing Cui  Xiaochuan Chen
Institution:Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, PR China
Abstract:The concise and efficient synthesis of (+)-goniofufurone, (+)-7-epi-goniofufurone, (+)-crassalactones B and C were achieved in 6 to 7 steps from the known d-glucono-δ-lactone derivative 9. An acid-mediated cascade cyclization was employed to construct the furanofurone bicyclic framework in one-pot.
Keywords:Corresponding author    Styryllactone  Goniofufurone  Crassalactone  Total synthesis
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