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Recent advances in Gomberg-Backmann biaryl synthesis
Authors:Toru Amaya  Yuqing Jin  Mamoru Tobisu
Affiliation:Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan
Abstract:The Gomberg-Bachmann reaction is an intermolecular aryl-aryl cross-coupling reaction using an arenediazonium salt and an arene. This digest review surveys recent advances in the Gomberg-Bachmann reaction. More specifically, it focuses on reaction systems that include 1) transition-metal-induced systems, 2) organic promoter-induced systems, 3) electrolytic systems, 4) photoreaction systems, and 5) hybrid systems consisted of a photoredox and a transition-metal catalyst.
Keywords:Corresponding author.  Gomberg-Bachmann reaction  C-H arylation  Homolytic aromatic substitution  Radical chain reaction
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