Abstract: | We report the template‐free synthesis and characterization of a new type of porphyrin/quinoidal‐bithiophene‐based conjugated macrocycle. X‐ray crystallographic analysis of the dimer ( 2MC ) revealed a cyclophane‐like geometry with large dihedral angles between the porphyrin and the neighboring thiophene rings, and NMR measurements and theoretical calculations confirmed a localized aromatic character of the porphyrin/thiophene rings and quinoidal character of the bithiophene linkers. Restricted rotation of the thiophene rings linked to the porphyrin unit was observed by variable‐temperature NMR measurements. The dication ( 2MC2+ ) adopts a chair‐shaped conformation to facilitate π‐electron delocalization around the whole macrocycle. As a result, the molecule is globally aromatic, with a dominant 54 π conjugation pathway. The trimer ( 3MC ) also shows localized aromatic character of porphyrin rings and conformational flexibility, but its dication ( 3MC2+ ) is rigid and globally aromatic with a dominant 82 π conjugation pathway. |