New approach to the synthesis of tetrazole-containing buta-1,3-diynes: The total synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne |
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| Authors: | George K Belousov Alexander V Zuraev |
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| Institution: | 1. Belarusian State University, Nezalezhnastsi Avenue 4, 220050 Minsk, Belarus;2. Research Institute for Physical Chemical Problems of Belarusian State University, Leningradskaya 14, 220006 Minsk, Belarus |
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| Abstract: | An approach for the total synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne was reported. Developed approach to the synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne can be used for obtaining different 2,5-bis(tetrazol-5-yl)-disubstituted five-membered heterocycles (e.g. thiophenes, pyrroles, furans etc.), as well as tetrazole-containing monomers for the synthesis of new types of electroconductive and high energetic polymers. |
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| Keywords: | Corresponding author at: Belarusian State University Nezalezhnastsi Avenue 4 220050 Minsk Belarus Alkynes Buta-1 3-diynes Cross-coupling |
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