Total synthesis,reactivity, and structural clarification of lindenatriene |
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| Authors: | James M Eagan Kyalo Stephen Kanyiva Masahiro Hori Scott A Snyder |
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| Institution: | 1. Department of Chemistry, Columbia University, 3000 Broadway, New York, NY 10027, USA;2. Department of Chemistry, University of Chicago, 5735 S. Ellis Avenue, Chicago, IL 60637, USA |
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| Abstract: | The synthesis of lindenatriene (1) and iso-lindenatriene (12) were achieved, along with the des-hydroxy model compounds (10 and 18, respectively), and compared to reported 1H NMR spectra in the literature (1a and 10a). These comparisons clarify the correct initial assignment of lindenatriene (1) as well as its instability and propensity to isomerize into the more thermodynamically favored iso-lindenatriene (12). |
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| Keywords: | Corresponding author Department of Chemistry University of Chicago 5735 S Ellis Avenue Chicago IL 60637 USA Sesquiterpene Natural products Total synthesis Dimer |
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