Cascade reaction for the synthesis of polycyclic aromatic hydrocarbons via transient directing group strategy |
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Authors: | Ziqi Wang Wendan Dong Bing Sun Qinqin Yu Fang-Lin Zhang |
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Institution: | School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, PR China |
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Abstract: | A Pd(II)-catalyzed cascade synthesis of diverse polycyclic aromatic hydrocarbons via transient directing group strategy has been developed, involving the consecutive arylation, cyclization and aromatization. The efficiency and practicality were demonstrated by wide substrate range, concise synthetic pathway and mild reaction conditions. The subsequent transformations of the benza]anthracene core accessed natural bioactive PAH molecules. |
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Keywords: | Corresponding author Palladium Cascade Polycyclic aromatic hydrocarbons Transient directing group Bioactive molecules |
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