Aqueous metal-free hydrothiolation of enamides and enecarbamates |
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| Authors: | Eliezer Barman Jason Hourezadeh Daniel Lim |
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| Institution: | Department of Chemistry, Yeshiva University, 500 W 185th St, New York, NY 10033, USA |
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| Abstract: | An efficient and metal-free, anti-Markovnikov selective, hydrothioaltion reaction of enamides and enecarbamates in an aqueous medium is presented. This protocol is operationally simple, mild, and atom-economical. This process provides access to thioethers from available thiols and a variety of enamides and enecarbamates. |
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| Keywords: | Corresponding author Metal-free Hydrothiolation Anti-markovnikov Thiol-Ene |
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