Iridium(III) Tris-cyclometalated Complexes with Diphenyloxazolic Ligands: Influence of Ligand Structure on Electrochemical and Photophysical Properties期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Iridium(III) Tris-cyclometalated Complexes with Diphenyloxazolic Ligands: Influence of Ligand Structure on Electrochemical and Photophysical Properties

Authors:	Vladislav?V.?Krisyuk author-information" > author-information__contact u-icon-before" > mailto:kvv@che.nsk.su" title=" kvv@che.nsk.su" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,Assia?E.?Turgambaeva,Jiyeon?Lee,Shi-Woo?Rhee

Affiliation:	(1) Nikolaev Institute of Inorganic Chemistry SB RAS, Pr. Lavrentieva 3, Novosibirsk, 630090, Russia;(2) Laboratory for Advanced Molecular Processing, Department of Chemical Engineering, Pohang University of Science and Technology, San 31 Hyoja-Dong, Nam-Gu, Pohang, 790-784, Korea

Abstract:	Two luminescent iridium(III) tris-cyclometalated complexes with isomeric 2,4-diphenyloxazolato and 2,5-diphenyloxazolato ligands, fac-Ir(24dpo)₃ and fac-Ir(25dpo)₃, are reported. The molecular structure for Ir(24dpo)₃ was determined by X-ray diffraction. Electrochemical and spectroscopic studies supported by structures are discussed so as to demonstrate how the ligand structure influences the luminescent properties.

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