Experimente und Berechnungen zur Hyperfeinstruktur der 3d 9 5g-Konfiguration im Kupfer II-Spektrum

The 3d ⁹ 5g-configuration in the Cu II-spectrum is an example for extreme(j _d l _g )K-coupling. It is shown how under these circumstances experimental hyperfinestructure separations can be explained and calculated by means of the concept of intermediate coupling between two basic coupling schemes. The basic schemes used are built on the vectorK coupled either to the spins of the outer 5g-electron or to the nuclear spinI. The value of the experimental magnetic separation factorya _j (3d) can be understood as the consequence of the core polarization of the inners-electrons by the spin of the unfilled 3d-shell. — The measured effective spin-orbit-constantζ _5g is three times larger than the theoretical result. Reasons for this discrepancy will be discussed.