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14N and35Cl nuclear quadrupole double resonance study of the structural phase transitions in N-octylammoniumchloride
Authors:J. Seliger  V. Žagar  R. Blinc  R. Kind  H. Arend  F. Milia
Affiliation:(1) J. Stefan Institute, E. Kardelj University of Ljubljana, Jamova 39/p.p. 100, Yu-61111 Ljubljana, Yugoslavia;(2) Laboratory of Solid State Physics, Swiss Federal Institute of Technology, Zürich, Switzerland;(3) Nuclear Research Center Demokritos, Aghia Paraskevi Attikis, Athens, Greece
Abstract:The structural phase transitions between the non-intercalated phases of the layer structure compound N-octylammoniumchloride have been studied via proton-14N and proton-35Cl nuclear quadrupole double resonance. The results have been related to an order-disorder model of the octylammonium chains. The temperature dependence of the order parameters of the –NH3 head groups has been determined.
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