Synthesis, crystal structure, and solid-state NMR spectroscopy of a salt-inclusion stannosilicate: [Na3F][SnSi3O9 |
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Authors: | Liao Chen-Hui Chang Pai-Ching Kao Hsien-Ming Lii Kwang-Hwa |
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Affiliation: | Department of Chemistry, National Central University, Chungli, Taiwan, Republic of China. |
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Abstract: | A salt-inclusion stannosilicate, [Na3F][SnSi3O9], has been synthesized using a flux-growth method and characterized by single-crystal X-ray diffraction. The structure consists of six-membered silicate rings linked via corner sharing by SnIVO6 octahedra to form a 3-D framework that delimits two types of channels. The F atoms and Na atoms are located in the structural channels and form a dimer with the anti-Al2Cl6(g) structure. This stannosilicate adopts a new structure and is the first metal silicate that contains both Na+ and F- ions in the channels. The 19F and 29Si MAS NMR and 23Na MQMAS NMR spectra are consistent with the crystallographic results. |
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