Untersuchungen zum Bildungsmechanismus von Molsieben |
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Authors: | B. Fahlke,W. Wieker,H. Fü rtig,W. Roscher,R. Seidel |
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Abstract: | Investigations on the Mechanism of Molecular Sieve Formation By means of chemical methods it is shown that the formation of zeolithic molecular sieves proceeds via the following stages: Precipitation of strongly SiO2 containing amorphous products, having varying compositions and containing high-condensed silicate anions; dissolution of these primary products under formation of low-molecular silicate anions; precipitation of a further intermediary product, having, however, a constant composition and containing low-molecular anions (mono- and disilicate); finally, transformation of this intermediate, partially under a further alteration of the silicate anion type, into the crystalline molecular sieve. |
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