|
|||||
|
|
| 氧化钆对铁磷酸盐玻璃结构的影响 | |
| 引用本文： | 赖元明,梁晓峰,钱 斌,高 龙,杨世源,尹光福. 氧化钆对铁磷酸盐玻璃结构的影响[J]. 无机化学学报, 2012, 28(4): 721-726 |
| 作者姓名： | 赖元明 梁晓峰 钱 斌 高 龙 杨世源 尹光福 |
| 作者单位： | 1. 西南科技大学,四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地,绵阳621010 2. 西南科技大学,四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地,绵阳621010;四川大学材料科学与工程学院,成都610065 3. 四川大学材料科学与工程学院,成都,610065 |
| 基金项目： | 四川省非金属复合与功能材料重点实验室一省部共建国家重点实验室培育基地开放基金(No.10zxfk14);西南科技大学研究生创新基金(No.11ycjj01)资助项目 |
| 摘 要： | 为探究Gd2O3含量对40Fe2O3-60P2O5(mol%)基础玻璃结构的影响,采用传统熔融-冷却法制备xGd2O3-(100-x)(40Fe2O3-60P2O5)(0≤x≤12mol%)系列玻璃。利用XRD、SEM、FTIR和Raman等手段对玻璃结构进行表征,并测试了玻璃密度和维氏硬度。结果表明,在Gd2O3含量小于等于4mol%时,易形成均质玻璃,在此范围内,玻璃密度和硬度都随Gd2O3含量的增加而增加,玻璃结构以焦磷酸盐结构为主,并伴随少量的正磷酸盐和偏磷酸盐结构。在磷酸盐玻璃结构中,Gd3+作为网络修饰离子,位于玻璃网络结构间隙。 |
| 关 键 词： | 铁磷酸盐 氧化钆 玻璃结构 |
Influence of Gadolinium Oxide on Structure of Iron Phosphate Glasses |
|
| LAI Yuan-Ming,LIANG Xiao-Feng,QIAN Bin,GAO Long,YANG Shi-Yuan and YIN Guang-Fu. Influence of Gadolinium Oxide on Structure of Iron Phosphate Glasses[J]. Chinese Journal of Inorganic Chemistry, 2012, 28(4): 721-726 | |
| Authors: | LAI Yuan-Ming LIANG Xiao-Feng QIAN Bin GAO Long YANG Shi-Yuan YIN Guang-Fu |
| Affiliation: | State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China,State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China; School of Materials Science and Engineering, Sichuan University, Chengdu 610065, China,State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China,State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China,State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China and School of Materials Science and Engineering, Sichuan University, Chengdu 610065, China |
| Abstract: | The glass samples with composition xGd2O3-(100-x)(40Fe2O3-60P2O5)(0≤x≤12mol%) have been prepared by the conventional melt quench method.The structure of the studied glasses have been investigated using X-ray diffraction(XRD),Scanning electron microscope(SEM),Fourier transform infrared spectroscopy(FTIR) and Raman spectra.The compositions containing up to 4mol% of Gd2O3 formed glasses.Density and hardness of the studied glasses increase with addition Gd2O3 content.FTIR and Raman data suggest that the addition 4mol% Gd2O3 in the 40Fe2O3-60P2O5(mol%) glass does not produce any fundamental change in structure of the phosphate network,which consists of predominantly pyrophosphate groups with a small proportion of metaphosphate and orthophosphate groups.From all these considerations we can conclude that Gd2O3 enters in the structure of studied glasses as a network modifier. |
| Keywords: | iron phosphate gadolinium oxide glass structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ | |
| 点击此处可从《无机化学学报》浏览原始摘要信息 | |
| 点击此处可从《无机化学学报》下载全文 | |