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| 无压烧结合成高纯度Ti3SiC2粉体 | |
| 引用本文： | 杨 锋,李长生,唐 华,高庆侠,唐国钢,朱秉莹,曹可生.无压烧结合成高纯度Ti3SiC2粉体[J].无机化学学报,2012,28(4):703-709. |
| 作者姓名： | 杨 锋 李长生 唐 华 高庆侠 唐国钢 朱秉莹 曹可生 |
| 作者单位： | 1. 江苏大学机械工程学院 江苏省摩擦学重点实验室,镇江,212013 2. 江苏大学机械工程学院 江苏省摩擦学重点实验室,镇江212013;江苏大学材料科学与工程学院,镇江212013 3. 江苏大学材料科学与工程学院,镇江,212013 4. 镇江高等专科学校化工系,镇江,212003 |
| 基金项目： | 国家自然科学基金(No.50471051);科技部“863”计划(No.2007AA03Z358)资助项目 |
| 摘 要： | 本文通过优化混合方式将Ti、Si、石墨和Al等粉末按照一定配比混合后,在1 420℃氩气保护下合成了Ti3SiC2粉末。用XRD和SEM分别分析了样品中的相成分、微观形貌,计算得出其质量百分含量,高达96.7%,研究了烧结工艺中降温速率对Ti3SiC2微观形貌的影响,并讨论了其生长机理。本工艺原料混合简单有效,得到的产品纯度高,因而有助于实现Ti3SiC2粉末的批量生产。 |
| 关 键 词： | Ti3SiC2粉末 无压烧结 降温速率 微观形貌 生长机理 |
Synthesis of High Purity Ti3SiC2 Powders with Pressureless Reactive Sintering |
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| YANG Feng,LI Chang-Sheng,TANG Hu,GAO Qing-Xi,TANG Guo-Gang,ZHU Bing-Ying and CAO Ke-Sheng.Synthesis of High Purity Ti3SiC2 Powders with Pressureless Reactive Sintering[J].Chinese Journal of Inorganic Chemistry,2012,28(4):703-709. | |
| Authors: | YANG Feng LI Chang-Sheng TANG Hu GAO Qing-Xi TANG Guo-Gang ZHU Bing-Ying and CAO Ke-Sheng |
| Institution: | School of Mechanical Engineering, Jiangsu University, Key Laboratory of Tribology of Jiangsu Province, Zhenjiang, Jiangsu 212013, China,School of Mechanical Engineering, Jiangsu University, Key Laboratory of Tribology of Jiangsu Province, Zhenjiang, Jiangsu 212013, China; School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China,School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China,School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China,Department of Chemical Engineering, Zhenjiang College, Zhenjiang, Jiangsu 212003, China,School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China and School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China |
| Abstract: | The Ti,Si,graphite and Al powders mixed according to certain proportion by optimizing the mixing methods,then the mixed powder was sintered at 1 420 ℃ for 2 hours under the protection of argon,pressureless reactive sintering synthesis Ti3SiC2 powder.X-ray diffraction(XRD) was applied to determine the phase compositions of the products,Calculate the Ti3SiC2 content of products,up to 96.7%.The structure and morphology of the products were characterized by SEM and the affect of the cooling rate on the morphology of Ti3SiC2 and the growth mechanism was discussed.Method of mixing of raw materials is simple and effective,purity of the product is high and this approach helps to achieve mass production of Ti3SiC2 powder. |
| Keywords: | Ti3SiC2 powder pressureless reactive sintering cooling rate morphology growth mechanism |
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