Characterization of CoMCM-41 mesoporous molecular sieves obtained by the microwave irradiation method |
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Authors: | Tingshun Jiang Wei Shen Mei Li Hengbo Yin |
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Institution: | a School of Chemistry and Chemical Engineering, Jiangsu University, Jiangsu Province 212013, PR China b School of Environment, Jiangsu University, Jiangsu Province 212013, PR China |
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Abstract: | CoMCM-41 mesoporous molecular sieves with different amounts of cobalt were synthesized via the microwave irradiation method. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), temperature programmed reduction (TPR), transmission electron microscopy (TEM) and N2 adsorption-desorption technique, and thermal and hydrothermal stabilities of synthesized CoMCM-41 samples were also investigated. Results show that these synthesized materials have typical mesoporous structure of MCM-41. Also, specific surface area and pore volume of synthesized CoMCM-41 decrease with increasing amount of cobalt added, and mesoporous ordering also decreases. When the molar ratio of SiO2:CoO in the starting material is 1.0:0.05, mesoporous ordering of synthesized CoMCM-41 is the best among the four doping contents. On the other hand, results of thermal and hydrothermal tests show that CoMCM-41 after calcination at 750 °C for 3 h or hydrothermal treatment at 100 °C for 5 days still retains mesostructure. However, mesoporous framework is entirely damaged after calcination at 850 °C for 3 h. |
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Keywords: | CoMCM-41 mesoporous molecular sieve Microwave irradiation method Characterization Stability Synthesis |
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