Free-radical addition of alkanethiols to 1-vinylpyrroles |
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Authors: | Mikhaleva A. I. Korostova S. E. Vasil'ev A. N. Balabanova L. N. Sokol'nikova N. P. Trofimov B. A. |
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Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, 664033 Irkutsk |
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Abstract: | In the presence of 2,2-azobisisobutyronitrile or in the absence of an initiator alkanethiols add to 1-vinylpyrroles exclusively counter to Markovnikov's rule to give 1-(2-alkylthioethyl)pyrroles (in yields up to 94%).Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1636–1639, December, 1977. |
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