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A selective etching phenomenon on {001} faceted anatase titanium dioxide single crystal surfaces by hydrofluoric acid
Authors:Wang Yun  Zhang Haimin  Han Yanhe  Liu Porun  Yao Xiangdong  Zhao Huijun
Institution:Centre for Clean Environment and Energy, and Griffith School of Environment, Gold Coast Campus, Griffith University, QLD 4222, Australia.
Abstract:A selective etching phenomenon on {001} faceted anatase TiO(2) single crystal surfaces by HF and associated etching mechanism are reported. Density functional theory (DFT) calculations reveal that HF stabilizes the grown {001} facets at low concentrations, but selectively destroys the grown {001} facets at high concentrations.
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