| 苯酚钾及对位取代苯酚钾的电离势 |
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| 引用本文： | 英柏宁 吴国湘. 苯酚钾及对位取代苯酚钾的电离势[J]. 高等学校化学学报, 1993, 14(6): 866-867 |
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| 作者姓名： | 英柏宁 吴国湘 |
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| 作者单位： | 中山大学化学系, 广州 510275 |
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| 摘 要： | 在我们以前的研究工作中发现,酚类钾盐是很好的电荷给体,可以和顺丁烯二酸酐、三硝基苯以及醌类等电荷受体生成电荷转移(CT)络合物。表示分子的给电子能力的参数是分子的第一电离势(简称为电离势I_p)。对于苯酚的I_p值,近年来已有文献记载,但苯酚钾
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| 关 键 词： | 苯酚钾 电荷转移光谱 电离势 |
| 收稿时间： | 1992-08-01 |
The lonization Potentials of Potassium Phenoxide and p-Substituted Phenoxides |
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| YING Bai-Ning,WU Guo-Xiang. The lonization Potentials of Potassium Phenoxide and p-Substituted Phenoxides[J]. Chemical Research In Chinese Universities, 1993, 14(6): 866-867 |
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| Authors: | YING Bai-Ning WU Guo-Xiang |
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| Affiliation: | Department of Chemistry, Zhongshan University, Guangzhou, 510275 |
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| Abstract: | t The interaction of phenol and its potassium salts as the electron donor with electron acceptor 7-nitro-5-phenyl-3H-1 ,4-benzodiazepin-2-(1H)one can form the charge transfer(CT) complexes in DMF. In this paper, with measuring the CT bands of CT complexes spectrophotometrically, the ionization potentials(IP) of potassium phenoxide and p-substituted phenoxides(p-RC6H4OK) have been determined in the comparision method. |
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| Keywords: | Potassium phenoxide Charge transfer spectra lonization potential |
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