Extraction of chlororuthenium(III) complexes from hydrochloric acid solutions by petroleum sulfoxides |
| |
| Authors: | N G Afzaletdinova L M Ryamova Yu I Murinov R V Kunakova |
| |
| Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia;(2) Ufa State Academy for Economics and Service, Ufa, Bashkortostan, Russia |
| |
| Abstract: | The extraction of ruthenium(II) by petroleum sulfoxides (PSOs) from hydrochloric acid solutions has been studied. The extraction of ruthenium(III) by PSOs is implemented by the coordination mechanism with the incorporation of the sulfoxide oxygen atom of the extractant into the inner coordination sphere of the ruthenium(III) ion. The composition of the extraction compound is suggested using electronic, 1H NMR, and IR spectroscopy, the slope method, and elemental analysis. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
