(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation
Abstract:
A general efficient method for the synthesis of phosphoryl isocyanates was developed. The method involves reactions of phosphoryl chlorides with sodium cyanate in the presence of anhydrous magnesium chloride as a catalyst. Dedicated to the Corresponding Member of the Russian Academy of Sciences T. A. Mastryukova. For the preliminary report, see Ref. 1. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2543–2545, November, 2005.