Synthesis and characterization of Cr-MSU-1 and its catalytic application for oxidation of styrene |
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Authors: | Hong Liu Zhigang Wang Yuguang Liang |
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Affiliation: | a Department of Chemical Engineering, Shanghai University, Shanghai 201800, PR China b College of Science, Shanghai University, Yanchang Road, Shanghai 200072, PR China |
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Abstract: | Chromium-containing mesoporous silica material Cr-MSU-1 was synthesized using lauryl alcohol-polyoxyethylene (23) ether as templating agent under the neutral pH condition by two-step method. The sample was characterized by XRD, TEM, FT-IR, UV-Vis, ESR, ICP-AES and N2 adsorption. Its catalytic performance for oxidation of styrene was studied. Effects of the solvent used, the styrene/H2O2 mole ratio and the reaction temperature and time on the oxidation of styrene over the Cr-MSU-1 catalyst were examined. The results indicate that Cr ions have been successfully incorporated into the framework of MSU-1 and the Cr-MSU-1 material has a uniform worm-like holes mesoporous structure. After Cr-MSU-1 is calcined, most of Cr3+ is oxidized to Cr5+ and Cr6+ in tetrahedral coordination and no extra-framework Cr2O3 is formed. The Cr-MSU-1 catalyst is highly active for the selective oxidation of styrene and the main reaction products over Cr-MSU-1 are benzaldehyde and phenylacetaldehyde. Its catalytic performance remains stable within five repeated runs and no leaching is noticed for this chromium-based catalyst. |
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Keywords: | Cr-MSU-1 Mesoporous molecular sieve Synthesis Oxidation of styrene |
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