| Multicompartment Micelles From π-Shaped ABC Block Copolymers |
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| 引用本文： | 夏俊,仲崇立.Multicompartment Micelles From π-Shaped ABC Block Copolymers[J].中国化学,2007,25(11):1732-1738. |
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| 作者姓名： | 夏俊 仲崇立 |
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| 作者单位： | Beijing Key Laboratory of Bioprocess, Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20676004）. |
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| 摘 要： |
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| 关 键 词： | 耗散结构 胶束 共聚物 计算模型 |
| 修稿时间： | 2007-03-20 |
Multicompartment Micelles From π-Shaped ABC Block Copolymers |
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| XIA, Jun ZHONG, Chong-LI.Multicompartment Micelles From π-Shaped ABC Block Copolymers[J].Chinese Journal of Chemistry,2007,25(11):1732-1738. |
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| Authors: | XIA Jun ZHONG Chong-LI |
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| Institution: | Beijing Key Laboratory of Bioprocess, Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | Dissipative particle dynamics simulations were performed on the morphology and structure of multicompartmerit micelles formed from n-shaped ABC block copolymers in water. The influences of chain architectures were studied in a systematic way, and a rich variety of morphologies were observed, such as spherical, wormlike, X-shaped, Y-shaped, ribbon-like, layered rod-like, layered disk-like, as well as network morphologies. The simulations show that the distance between the two grafts plays an important role in control of the morphology. Since n-shaped ABC block copolymers can be reduced to linear ABC and star ABC block copolymers, they are good model copolymers for studying the self-assembly of complex block copolymers into micelles. The knowledge obtained in this work as well as the new morphologies identified provide useful information for future rational design and synthesis of novel multicompartment micelles. |
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| Keywords: | dissipative particle dynamics multicompartment micelle n-shaped block copolymer computer modeling |
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