| 三正丁基膦参与的二苯联硒与吖啶及环氧化合物的开环反应 |
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| 引用本文： | 张万轩,叶康,阮珊,陈祖兴,夏清华. 三正丁基膦参与的二苯联硒与吖啶及环氧化合物的开环反应[J]. 中国化学, 2007, 25(11): 1758-1761. DOI: 10.1002/cjoc.200790325 |
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| 作者姓名： | 张万轩 叶康 阮珊 陈祖兴 夏清华 |
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| 作者单位： | Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, Hubei 430062, China |
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| 基金项目： | Project supported by Hubei Provincial Department of Education and Ministry-of-Education Key Laboratory for the Synthesis and Application of 0rganic Functional Molecules, Hubei University. |
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| 摘 要： | Aziridines and epoxides were reacted with diphenyl diselenide in the presence of a stoichiometric amount of （n-Bu）3P, respectively, giving β-amino- or β-hydroxy selenides in moderate to excellent yields under mild conditions. In the reactions the （n-Bu）3P might act as a reductant though it was a nucleophilic catalyst in other similar ring-opening reactions.
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| 关 键 词： | 环氧化物 环形开关 硒化物 还原反应 |
| 收稿时间： | 2007-04-05 |
| 修稿时间： | 2007-04-05 |
Tri-n-butylphosphine Mediated Ring-Opening Reactions of Aziridines or Epoxides with Diphenyl Diselenide |
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| ZHANG, Wan-Xuan YE, Kang RUAN, Shan CHEN, Zu-Xing XIA, Qing-Hua. Tri-n-butylphosphine Mediated Ring-Opening Reactions of Aziridines or Epoxides with Diphenyl Diselenide[J]. Chinese Journal of Chemistry, 2007, 25(11): 1758-1761. DOI: 10.1002/cjoc.200790325 |
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| Authors: | ZHANG Wan-Xuan YE Kang RUAN Shan CHEN Zu-Xing XIA Qing-Hua |
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| Affiliation: | Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, Hubei 430062, China |
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| Abstract: | Aziridines and epoxides were reacted with diphenyl diselenide in the presence of a stoichiometric amount of (n-Bu)3P, respectively, giving β-amino- or β-hydroxy selenides in moderate to excellent yields under mild conditions. In the reactions the (n-Bu)3P might act as a reductant though it was a nucleophilic catalyst in other similar ring-opening reactions. |
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| Keywords: | aziridine epoxide ring opening selenide reduction |
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