| 四甲氧基取代的二苯并并四苯(DBN)的合成, 晶体结构及聚集效应 |
| |
| 引用本文： | 程晓红,傅长金,. 四甲氧基取代的二苯并并四苯(DBN)的合成, 晶体结构及聚集效应[J]. 中国化学, 2007, 25(11): 1762-1765. DOI: 10.1002/cjoc.200790326 |
| |
| 作者姓名： | 程晓红 傅长金 |
| |
| 作者单位： | Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemistry and Material Engineering, Yunnan University, Kunming, Yunnan 650091, China |
| |
| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20472070） and the Natural Science Foundation of Yunnan Province, China （No. 2005E008M）. |
| |
| 摘 要： | 本文从商品化的间溴苯甲醚和对甲氧基苯甲醛出发，通过傅-克酰基化反应、串联的羟醛缩合及1,4-迈克尔加成反应，得到三芳基取代的1,5-二酮，然后用查尔酮（Chalcone）作氧化剂，二酮与BF3.Et2O 反应形成吡喃鎓盐，再与苯基乙酸钠盐缩合得到芳香二溴代衍生物，产物的DMA溶液在DBU和钯催化剂的作用下，160°C 加热12 h进行脱卤化氢环化反应, 生成四甲氧基取代的二苯并并四苯（DBN）类衍生物。并报道了产物的晶体结构和在溶液中的聚集效应。
|
| 关 键 词： | 萘并萘 化学合成 x射线结构 聚集反应 |
| 收稿时间： | 2006-07-28 |
| 修稿时间： | 2006-07-28 |
Synthesis, X-ray Structure and Aggregation Effect of Tetramethoxy Substituted Dibenzo[ fg, op]naphthacene |
| |
| CHENG, Xiao-Hong FU, Chang-Jin. Synthesis, X-ray Structure and Aggregation Effect of Tetramethoxy Substituted Dibenzo[ fg, op]naphthacene[J]. Chinese Journal of Chemistry, 2007, 25(11): 1762-1765. DOI: 10.1002/cjoc.200790326 |
| |
| Authors: | CHENG Xiao-Hong FU Chang-Jin |
| |
| Affiliation: | Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemistry and Material Engineering, Yunnan University, Kunming, Yunnan 650091, China |
| |
| Abstract: | Tetramethoxy substituted dibenzo[fg,op]naphthacene was synthesised by using Friedel-Crafts acylation, tandem Aldol-Michael solvent-free reaction and palladium catalyzed dehydrohalogenation cyclization as key steps. The X-ray structure of the product and its aggregation effect in solvent were also reported. |
| |
| Keywords: | dibenzo[fg op]naphthacene synthesis X-ray structure aggregation |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国化学》浏览原始摘要信息 |
|
点击此处可从《中国化学》下载全文 |
|
