Elektrochemische synthesen metallorganischer verbindungen III. Darstellung und umwandlung von π-cyclooctenyl-1,5-cyclooctadiencobalt |
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| Authors: | H Lehmkuhl W Leuchte and E Janssen |
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| Institution: | Max-Planck-Institut für Kohlenforschung, Mülheim a.d. Ruhr Deutschland |
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| Abstract: | By electrolysis of cobalt(II)-acetylacetonate in the presence of 1,5-cyclooctadiene there is obtained π-cyclooctenyl-1,5-cyclooctadienecobalt (I). By heating of I to 60° in 1,5-cyclooctadiene, π-bicyclo3.3.0]octadienyl-(1,5-cyclooctadiene)cobalt (II) and cyclooctene are formed. |
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