| 交替马来酸酐共聚物多缩乙二醇酯盐络合物的离子传导性 |
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| 引用本文： | 丁黎明,林云青.交替马来酸酐共聚物多缩乙二醇酯盐络合物的离子传导性[J].高等学校化学学报,1994,15(11):1727-1729. |
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| 作者姓名： | 丁黎明 林云青 |
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| 作者单位： | 中国科学院长春应用化学研究所, 长春, 130022 |
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| 摘 要： | 交替马来酸酐共聚物多缩乙二醇酯盐络合物的离子传导性丁黎明，林云青，周子南，王佛松（中国科学院长春应用化学研究所，长春，１３００２２）关键词高分子固体电解质，离子电导率，玻璃化转变温度，离子传输，ＶＴＦ方程１９７３年，Ｐ．Ｖ．Ｗｒｉｇｈｔ等人［１］首次...
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| 关 键 词： | 高分子固体电解质 离子电导率 玻璃化转变温度 离子传输 VTF方程 |
| 收稿时间： | 1993-11-03 |
Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains |
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| DING Li-Ming,LIN Yun-Qing,ZNOU Zi-Nan,WANG Fo-Song.Ionic Conduction of Polymer Electrolytes Based on an Alternating Maleic Anhydride Copolymer with Oligo-oxyethylene Side Chains[J].Chemical Research In Chinese Universities,1994,15(11):1727-1729. |
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| Authors: | DING Li-Ming LIN Yun-Qing ZNOU Zi-Nan WANG Fo-Song |
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| Institution: | Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022 |
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| Abstract: | In this paper, the ionic conductivity of the BM350-LiClO4 complexes was studied as a function of temperature and salt concentration.At high salt concentrations,the more pronounced fall in conductivity in the solid medium has been interpreted as being due to the effect of Tg and bulk viscosity on ion transport. Conductivities which displayed non-Arrhe-nius behviour were analysed using the Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model derived by Gibbs and coworkers. |
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| Keywords: | Solid polymer electrolytes Ionic conductivity Glass transition temperature Ion transport VTF equation |
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