Synthesis of the elusive (R3P)2MF2 (M = Pd, Pt) complexes |
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| Authors: | Yahav Anette Goldberg Israel Vigalok Arkadi |
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| Affiliation: | School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel. |
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| Abstract: | The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands. |
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