Photochemical Sandmeyer-type Halogenation of Arenediazonium Salts |
| |
| Authors: | Nardana Sivendran Florian Belitz Daniel Sowa Prendes Dr Ángel Manu Martínez Prof?Dr Rochus Schmid Prof?Dr Lukas J Gooßen |
| |
| Institution: | Department of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätsstr. 150, 44801 Bochum, Germany |
| |
| Abstract: | Trihalide salts were found to efficiently promote photochemical dediazotizing halogenations of diazonium salts. In contrast to classical Sandmeyer reactions, no metal catalysts are required to achieve high yields and outstanding selectivities for halogenation over competing hydridodediazotization. Convenient protocols are disclosed for synthetically meaningful brominations, iodinations, and chlorinations of diversely functionalized derivatives. |
| |
| Keywords: | |
|
|
