Enhancement of Mass and Charge Transfer during Carbon Dioxide Photoreduction by Enhanced Surface Hydrophobicity without a Barrier Layer |
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| Authors: | Xuan Liu Dr. Chengxi Huang Dr. Bo Ouyang Dr. Yongping Du Boyu Fu Zhengwei Du Qiang Ju Dr. Jingjing Ma Prof. Dr. Ang Li Prof. Dr. Erjun Kan |
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| Affiliation: | 1. MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing, Department of Applied Physics, Nanjing University of Science and Technology, Nanjing, 210094 P. R. China;2. State Key Laboratory of High-efficiency Utilization of, Coal and Green Chemical Engineering, Ningxia University, Ningxia, 750021 P. R. China |
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| Abstract: | The CO2 reduction reaction (CRR) represents a promising route for the clean utilization of renewable resources. But mass-transfer limitations seriously hinder the forward step. Enhancing the surface hydrophobicity by using polymers has been proved to be one of the most efficient strategies. However, as macromolecular organics, polymers on the surface hinder the transfer of charge carriers from catalysts to reactants. Herein, we describe an in-situ surface fluorination strategy to enhance the surface hydrophobicity of TiO2 without a barrier layer of organics, thus facilitating the mass transfer of CO2 to catalysts and charge transfer. With less obstruction to charge transfer, a higher CO2, and lower H+ surface concentration, the photocatalytic CRR generation rate of methanol (CH3OH) is greatly enhanced to up to 247.15 μmol g−1 h−1. Furthermore, we investigated the overall defects; enhancing the surface hydrophobicity of catalysts provides a general and reliable method to improve the competitiveness of CRR. |
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| Keywords: | carbon dioxide reduction in-situ hydrophobic modification organic barrier layers titanium dioxide transfer limitations |
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