Ferroelasticity in Organic–Inorganic Hybrid Perovskites

Molecular ferroelastics have received particular attention for potential applications in mechanical switches, shape memory, energy conversion, information processing, and solar cells, by taking advantages of their low-cost, light-weight, easy preparation, and mechanical flexibility. The unique structures of organic–inorganic hybrid perovskites have been considered to be a design platform for symmetry-breaking-associated order–disorder in lattice, thereby possessing great potential for ferroelastic phase transition. Herein, we review the research progress of organic–inorganic hybrid perovskite ferroelastics in recent years, focusing on the crystal structures, dimensions, phase transitions and ferroelastic properties. In view of the few reports on molecular-based hybrid ferroelastics, we look forward to the structural design strategies of molecular ferroelastic materials, as well as the opportunities and challenges faced by molecular-based hybrid ferroelastic materials in the future. This review will have positive guiding significance for the synthesis and future exploration of organic–inorganic hybrid molecular ferroelastics.