| 镧系四元混合阴离子配合物［Ce(p-MBA)2(NO3)(phen)］2的合成和晶体结构 |
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| 引用本文： | 咸春颖,朱龙观,俞庆森. 镧系四元混合阴离子配合物［Ce(p-MBA)2(NO3)(phen)］2的合成和晶体结构[J]. 无机化学学报, 1999, 15(6): 813-816 |
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| 作者姓名： | 咸春颖 朱龙观 俞庆森 |
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| 作者单位： | 1. 浙江大学化学系,杭州,310027
2. 日本京都大学合成化学和生物化学系 |
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| 摘 要： | We synthesized new mixed anion complex of lanthanide ［Ce(p-MBA)2(NO3)(phen)］2 in slightly acidic solution of ethanol and determined the single crystal structure. The title complex is triclinic, space group P1, a=1.1027(4) nm, b=1.2511(5) nm, c=1.0633(3) nm, α=106.90(3)°, β=96.73(3)°, γ=86.85(3)°, V=1.3937(9) nm3, DC=1.555 g·cm-3, Z=1, F(000)=650.00 and μ(MoKα)=16.82 cm-1. The four p-MBA ligands have two kinds of coordination modes and the coordination number of the Ce3+ is nine. There is some aromatic-stacking interaction in the benzene rings of two p-MBA ligands.
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| 关 键 词： | 混合阴离子 晶体结构 配合物 |
| 修稿时间： | 1999－01－15 |
SYNTHESIS AND CRYSTAL STRUCTURE OF MIXED ANION COMPLEX OF LANTHANIDE [Ce(p-CH3C6H4COO)2(NO3)(phen)]2 |
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| XIAN Chun-Ying,ZHU Long-Guan and YU Qing-Sen. SYNTHESIS AND CRYSTAL STRUCTURE OF MIXED ANION COMPLEX OF LANTHANIDE [Ce(p-CH3C6H4COO)2(NO3)(phen)]2[J]. Chinese Journal of Inorganic Chemistry, 1999, 15(6): 813-816 |
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| Authors: | XIAN Chun-Ying ZHU Long-Guan YU Qing-Sen |
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| Affiliation: | Department of Chemistry, Zhejiang University, Hangzhou 310027,Department of Chemistry, Zhejiang University, Hangzhou 310027 and Department of Chemistry, Zhejiang University, Hangzhou 310027 |
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| Abstract: | |
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| Keywords: | mixed anions crystal structure complex |
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