Ring inversion kinetics of radicals derived from Mu addition to cycloheptatriene |
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| Authors: | M. Heming E. Roduner |
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| Affiliation: | 1. Physik-Chemisches Institut der Universit?t Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland
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| Abstract: | Upon injection of spin-polarized positive muons into cycloheptatriene three radicals have been observed by transverse field μSR. The temperature dependence of the relaxation rates have been interpreted in terms of a rapid inversion process. The Arrhenius parameters have been determined and an isotope effect with respect to the barrier height of the inversion has been found. |
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