Demethylation of 2,4-dimethoxyquinolines: the synthesis of atanine |
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| Authors: | Jones Keith Roset Xavier Rossiter Sharon Whitfield Philip |
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| Institution: | Department of Chemistry, King's College London, Strand, London, UK WC2R 2LS. keith.jones@kingston.ac.uk |
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| Abstract: | The synthesis of the quinoline alkaloid atanine 6, by selective demethylation of the 2,4-dimethoxyquinoline 11 is presented. An alternative demethylation utilising a thiolate anion leads to the regioisomeric 4-hydroxyquinoline 13. |
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