Synthesis, Crystal Structure and Magnetic Property of Sanwich-Type Heteropolyoxometalate Na_9[{Na(H_2O)_2}_3{Cu(H_2O)}_3(BiW_9O_(33))_2]·42H_2O |
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作者姓名: | 薛岗林 王虎林 谢志海 史启祯 王继武 王大奇 |
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作者单位: | Department of Chemistry,Northwest University,Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Xi'an,Shaanxi 710069,China State Key Laboratory of Coordination,Nanjing University,Nanjing,Jiangsu 210093,China,Department of Chemistry,Northwest University,Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Xi'an,Shaanxi 710069,China,Department of Chemistry,Northwest University,Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Xi'an,Shaanxi 710069,China,Department of Chemistry,Northwest University,Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Xi'an,Shaanxi 710069,China,Shaanxi Key Laboratory of Chemical Reaction Engineering,Yan'an University,Yan'an,Shaanxi 716000,China,Department of Chemistry,Liaocheng University,Liaocheng,Shandong 252000,China |
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基金项目: | Project supported by Visiting Scholar Foundation of Key Lab in Chinese Universities and the Education Commission of Shaanxi Province (No. 03JK077). |
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摘 要: | Introduction The chemistry of the sandwich-type heteropoly-oxometalates encapsulating clusters of early transition metals is current of considerable interest with respect to the application of complexes in material science, medi-cine, catalysis and fundamental perspectives.1-4 The great advantage of these complexes is the possibility of varying either the type of the metallic cluster or the het-eroatom. The proximity of the transition metals pos-sessing unpaired electrons facilitates their cou…
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