| Synthesis, Crystal Structure and Magnetic Property of Sanwich-Type Heteropolyoxometalate Na_9[{Na(H_2O)_2}_3{Cu(H_2O)}_3(BiW_9O_(33))_2]·42H_2O |
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| 引用本文： | 薛岗林,王虎林,谢志海,史启祯,王继武,王大奇.Synthesis, Crystal Structure and Magnetic Property of Sanwich-Type Heteropolyoxometalate Na_9[{Na(H_2O)_2}_3{Cu(H_2O)}_3(BiW_9O_(33))_2]·42H_2O[J].中国化学,2004(2). |
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| 作者姓名： | 薛岗林 王虎林 谢志海 史启祯 王继武 王大奇 |
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| 作者单位： | Department of Chemistry，Northwest University，Shaanxi Key Laboratory of Physico-Inorganic Chemistry，Xi'an，Shaanxi 710069，China State Key Laboratory of Coordination，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Northwest University，Shaanxi Key Laboratory of Physico-Inorganic Chemistry，Xi'an，Shaanxi 710069，China，Department of Chemistry，Northwest University，Shaanxi Key Laboratory of Physico-Inorganic Chemistry，Xi'an，Shaanxi 710069，China，Department of Chemistry，Northwest University，Shaanxi Key Laboratory of Physico-Inorganic Chemistry，Xi'an，Shaanxi 710069，China，Shaanxi Key Laboratory of Chemical Reaction Engineering，Yan'an University，Yan'an，Shaanxi 716000，China，Department of Chemistry，Liaocheng University，Liaocheng，Shandong 252000，China |
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| 基金项目： | Project supported by Visiting Scholar Foundation of Key Lab in Chinese Universities and the Education Commission of Shaanxi Province (No. 03JK077). |
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| 摘 要： | Introduction The chemistry of the sandwich-type heteropoly-oxometalates encapsulating clusters of early transition metals is current of considerable interest with respect to the application of complexes in material science, medi-cine, catalysis and fundamental perspectives.1-4 The great advantage of these complexes is the possibility of varying either the type of the metallic cluster or the het-eroatom. The proximity of the transition metals pos-sessing unpaired electrons facilitates their cou…
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