The primary investigation of optical-limiting effects of optical active phthalocyanine derivative TMBO-SiPc |
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Authors: | Shuang Zhang Peiji WuCheng Ye Hongwei Liu Fu Xi |
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Institution: | a Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Zhongguancun, Beijing 100080, People's Republic of China b Graduate School of The Chinese Academy of Sciences, Beijing 100080, People's Republic of China |
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Abstract: | The optical-limiting property of an optically active phthalocyanine derivative with different configuration in chloroform solution was measured at 532 nm with 10 ns pulses. The excited state absorption cross-section σex of the derivative was determined with the Z-scan technique. The results showed that the phthalocyanine derivative possesses larger σex than the ground state absorption cross-section σ0, indicating that it is a material for reverse saturable absorption. And it is specially noticed that the change in the optically active configuration affects its optical-limiting property significantly. |
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Keywords: | 42 65&minus k 42 65 Vh 42 70 Nq |
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