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The primary investigation of optical-limiting effects of optical active phthalocyanine derivative TMBO-SiPc
Authors:Shuang Zhang  Peiji WuCheng Ye  Hongwei Liu  Fu Xi
Institution:a Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Zhongguancun, Beijing 100080, People's Republic of China
b Graduate School of The Chinese Academy of Sciences, Beijing 100080, People's Republic of China
Abstract:The optical-limiting property of an optically active phthalocyanine derivative with different configuration in chloroform solution was measured at 532 nm with 10 ns pulses. The excited state absorption cross-section σex of the derivative was determined with the Z-scan technique. The results showed that the phthalocyanine derivative possesses larger σex than the ground state absorption cross-section σ0, indicating that it is a material for reverse saturable absorption. And it is specially noticed that the change in the optically active configuration affects its optical-limiting property significantly.
Keywords:42  65&minus  k  42  65  Vh  42  70  Nq
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