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Synthesis of Mesoporous Lanthanum Phosphate and Its Use as a Novel Sorbent
作者姓名:ANBIA Mansur  ROFOUEI Mohammad K.  HUSAIN Syed Waqif
作者单位:ANBIA Mansur ROFOUEI Mohammad K HUSAIN Syed Waqif~* Department of Applied Chemistry,Chemistry Faculty,University of Tarbiat Moallem,Tehran-15614,Iran
摘    要:Mesoporous lanthanum phosphate was synthesized by supramolecular self-assembly of cetyltrimethylammo-nium bromide and lanthanum nitrate following digestion in phosphoric acid.TGA-DTA,XRD and SEM were em-ployed to study the uncalcined and calcined materials.Sorption behavior of Cr(Ⅲ),Mn(Ⅱ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Cd(Ⅱ),Ba(Ⅱ),Hg(Ⅱ)and Pb(Ⅱ)cations was studied on such materials in water,3 mol·L~(-1)ammonia,0.01 mol.L~(-1)potassium ferrocyanide and 0.01 mol·L~(-1)potassium ferricyanide solutions.

关 键 词:合成  中孔磷酸镧  表面活性剂  金属阳离子吸附  吸附剂
收稿时间:2005-09-27
修稿时间:2005-09-272006-04-21

Synthesis of Mesoporous Lanthanum Phosphate and Its Use as a Novel Sorbent
ANBIA Mansur,ROFOUEI Mohammad K.,HUSAIN Syed Waqif.Synthesis of Mesoporous Lanthanum Phosphate and Its Use as a Novel Sorbent[J].Chinese Journal of Chemistry,2006,24(8):1026-1030.
Authors:ANBIA  ;Mansur;ROFOUEI  ;Mohammad;K;HUSAIN  ;Syed;Waqif
Abstract:Mesoporous lanthanum phosphate was synthesized by supramolecular self‐assembly of cetyltrimethylammonium bromide and lanthanum nitrate following digestion in phosphoric acid. TGA‐DTA, XRD and SEM were employed to study the uncalcined and calcined materials. Sorption behavior of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Ba(II), Hg(II) and Pb(II) cations was studied on such materials in water, 3 mol·L?1 ammonia, 0.01 mol·L?1 potassium ferrocyanide and 0.01 mol·L?1 potassium ferricyanide solutions.
Keywords:mesoporous  surfactant  lanthanum phosphate  metal cation sorption
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