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The tuneable complexation of gold nanoparticles
Authors:Cooke Graeme  Garety James F  Hewage Shanika Gunatilaka  Rabani Gouher  Rotello Vincent M  Woisel Patrice
Affiliation:WestCHEM Centre for Supramolecular Electrochemistry, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK. graemec@chem.gla.ac.uk
Abstract:Mixed monolayer protected gold nanoparticles have been fabricated incorporating 1,5-dialkyloxynaphthalene moieties that are capable of forming complexes with the tetracationic cyclophane cyclobis(paraquat-p-phenylene); electrochemical reduction of the cyclophane or the addition of tetrathiafulvalene results in disassembly of the complexes.
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