The tuneable complexation of gold nanoparticles |
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Authors: | Cooke Graeme Garety James F Hewage Shanika Gunatilaka Rabani Gouher Rotello Vincent M Woisel Patrice |
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Affiliation: | WestCHEM Centre for Supramolecular Electrochemistry, Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK. graemec@chem.gla.ac.uk |
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Abstract: | Mixed monolayer protected gold nanoparticles have been fabricated incorporating 1,5-dialkyloxynaphthalene moieties that are capable of forming complexes with the tetracationic cyclophane cyclobis(paraquat-p-phenylene); electrochemical reduction of the cyclophane or the addition of tetrathiafulvalene results in disassembly of the complexes. |
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