| A Facile and Efficient Synthesis of N,N—Dimethylarylamines from Aryl Bromides |
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| 作者姓名： | YanGuangWANG JianKuiZHAO |
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| 作者单位： | DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027 |
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| 摘 要： | Catalytie amination of aryl bromides with in situ generated dimethylamines from N,N-dimethylacetamide(DMA)has been suceessfully carried out using Ni(phen)Cl2 as catalyst,Both electron-rich and electron-poor aromatie system reaeted smoothly under the conditions to give N,N-dimethylarylamines in good yields.
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| 关 键 词： | amination cross－coupling reaction N N－Dimethylarylamines ArylBromide 镍催化 N N－二甲基乙酰胺 N N－dimethylacetamide DMA |
A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides |
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| YanGuangWANG JianKuiZHAO.A Facile and Efficient Synthesis of N,N-Dimethylarylamines from Aryl Bromides[J].Chinese Chemical Letters,2002,13(12):1149-1151. |
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| Authors: | Jian Kui ZHAO Yan Guang WANG |
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| Abstract: | Catalytic amination of aryl bromides with in situ generated dimethylamines from N, N- dimethylacetamide (DMA) has been successfully carried out using Ni(Phen)Cl2 as catalyst. Both electron-rich and electron-poor aromatic system reacted smoothly under the conditions to give N,N-dimethylarylamines in good yields. |
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| Keywords: | Amination nickel-catalyzed cross-coupling reaction N N-dimethylarylamine |
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