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Generation of Hydrogen from Photolysis of Organic Acids by Photosynthetic Bacteria
作者姓名:SuPingYANG  ZhengWuWANG
作者单位:[1]StateKeyLaboratoryofMicrobialTechnology,ShandongUniversity,Jinan250100 [2]KeyLabofColloidandInterfaceChemistryforStateEducationMinistry,ShandongUniversity,Jinan250100
摘    要:Photodccomposition of ten kinds of organic acids by Rhodopseudomonas palustris for producing hydrogen has been investigated,By using acctate as hydrogen donor,dynamics of hydrogen production and cell growth has been determined;the influences of acetate concentration,temperature,light intensity and the effects of the ineraction among metal ions (Fe^3 ,Ni^ ),acctate and glutamatc in aqueous solution on hydrogen production have been examined for optimizing the conditions of H2 generation .The results show that H2 production is partially correlated with cell growth ;Ni^2 inhibits hydrogen production,but enhances cell growth; Fe^3 promotes hydrogen production evidcntly,The highest rate of H2 production is 22.1 mL L^-1h^-1 under the conditions of 35-37℃,6000-8000lx,30 mmolL^-1 of acetate, 9mmolL^-1 of glutamate, and 50μmolL^-1 of Fe^3 .

关 键 词:有机酸  光合细菌  光解作用  氢气

Generation of Hydrogen from Photolysis of Organic Acids by Photosynthetic Bacteria
Su Ping YANG,Zheng Wu WANG,Chun Gui ZHAO,Yin Bo QU,Xin Min QIAN.Generation of Hydrogen from Photolysis of Organic Acids by Photosynthetic Bacteria[J].Chinese Chemical Letters,2002,13(11):1111-1114.
Authors:Su Ping YANG  Zheng Wu WANG  Chun Gui ZHAO  Yin Bo QU  Xin Min QIAN
Abstract:Photodecomposition of ten kinds of organic acids by Rhodopseudomonas palustris for producing hydrogen has been investigated. By using acetate as hydrogen donor, dynamics of hydrogen production and cell growth has been determined; the influences of acetate concentration, temperature, light intensity and the effects of the interaction among metal ions (Fe3+, Ni2+), acetate and glutamate in aqueous solution on hydrogen production have been examined for optimizing the conditions of H2 generation. The results show that H2 production is partially correlated with cell growth; Ni2+ inhibits hydrogen production, but enhances cell growth; Fe3+ promotes hydrogen production evidently. The highest rate of H2 production is 22.1 mL L-1 h-1 under the conditions of 35 ~ 37℃, 6000 ~ 8000 lx, 30 mmolL-1 of acetate, 9 mmolL-1 of glutamate, and 50 (molL-1 of Fe3+.
Keywords:Photodecomposition of organic acids  hydrogen  photosynthetic bacteria  
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