Electrochemical determination of diffusion coefficients of selected metals in dimethylsulfoxide |
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| Authors: | Jerry L Jones Herbert A Fritsche Jr |
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| Institution: | Department of Chemistry, Texas A&M University, College Station. Texas 77840 U.S.A. |
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| Abstract: | Diffusion coefficients of lead, zinc, thallium and gadolinium in dimethylsulfoxide have been measured electrochemically by means of the complete Koutecky equation. Instantaneous currents were measured on first drops from a D.M.E. and calculations were made by an iterative computer technique. Half-wave potentials, polarographic wave reversibility, and diffusion control data are reported. |
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