| 杯芳烃—卟啉键连化合物的合成及其紫外—可见光谱特性 |
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| 引用本文： | 袁立华,陈淑华,赵华明.杯芳烃—卟啉键连化合物的合成及其紫外—可见光谱特性[J].化学研究与应用,1992(4). |
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| 作者姓名： | 袁立华 陈淑华 赵华明 |
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| 作者单位： | 四川大学化学系，四川大学化学系，四川大学化学系 成都 61006，成都 61006，成都 61006 |
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| 基金项目： | 国家教委科学基金资助项目 |
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| 摘 要： | 本文合成了一种新型的杯芳烃-卟啉模型化合物5及其金属锌的络合物6,用紫外-可见光谱考察了引入对-叔丁基杯4]芳烃后对卟啉各特征吸收带的影响。
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| 关 键 词： | 合成 卟啉 杯芳烃 卟啉-杯芳烃 紫外-可见光谱 |
MOLECULAR DEVICE BY COMBINATION OF PORPHYRINE RESIDUE ON p-TERTI-BUTYLCALIX [4] ARENE AND ITS ZINC COMPLEX |
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| Yuan Lihua Chen Shuhua Zhao Huaming.MOLECULAR DEVICE BY COMBINATION OF PORPHYRINE RESIDUE ON p-TERTI-BUTYLCALIX [4] ARENE AND ITS ZINC COMPLEX[J].Chemical Research and Application,1992(4). |
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| Authors: | Yuan Lihua Chen Shuhua Zhao Huaming |
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| Abstract: | A novel molecular device by combination of porphyrine residue on p-tert-butylcalix4]arene 5 and its zinc complex 6, which may be employed as monooxygenase mimic, has been accomplished. Their structures havs been confirmed by IR,MS,~1HNMR and UV-vis spectra, The offect of the calixarene on UV-Vis spectra has of porphyrine 5 and 6 been investigated by comparison with porphyrin ester 2 and 3. A slight hypsochromic shift was observed for the zinc complex of 5 as compared with 3. |
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| Keywords: | Synthesis porphyrin calixarene porphyrin-calixarere UV-vis spectra |
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