The interaction of electron acceptors with bases—II The spectrum of s-trinitrobenzene in the presence of ammonia and aliphatic amines |
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| Authors: | R. Foster and R. K. Mackie |
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| Affiliation: | Chemistry Department, Queen's College, University of St. Andrews, Dundee U.S.A. |
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| Abstract: | The interaction of s-trinitrobenzene with certain aliphatic amines has been studied spectrophotometrically. It is suggested in solutions in ethanol or chloroform, an adduct is initially formed by a dative bond between the nitrogen of the amine molecule and the 2-position in s-trinitrobenzene. The initial reactions are reversed by acid, but in time further irreversible reactions occur. |
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