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Polyfluorinated hydrazones in organic syntheses
Authors:G G Bargamov  M D Bargamova
Institution:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul., Vavilova, 117813 Moscow, Russian Federation
Abstract:The reaction of poly- and perfluoroaldehyde hydrazones with hydrazine hydrate was studied. A new preparative method for obtaining the hitherto inaccessibleN,N-unsubstituted bis-hydrazones of polyfluorinated agr-oxoaldehydes was developed based on this reaction.For Part 2, seeIzv. Akad. Nauk, Ser. Khim., 1995, 2465 Russ. Chem. Bull, 1995,44, 2360 (Engl. Transl.)].Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2526–2527, December, 1995.This study was financially supported by the Russian Foundation for Basic Research (Grant No. 94-03-08548) and the International Science Foundation (Grant Nos. NDL 000 and NDL 300).
Keywords:hydrazine hydrate  7-H-dodecafluoroheptanal  poly- and perfluoroaldehyde hydrazones  polyfluorinated agr-oxoaldehyde bis-hydrazones" target="_blank">gif" alt="agr" align="BASELINE" BORDER="0">-oxoaldehyde bis-hydrazones
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