Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones into 3,4-dimethylphenol |
| |
| Authors: | G V Gavrilova A A Moiseeva E K Beloglazkina A A Gavrilov N V Zyk |
| |
| Institution: | (1) Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia |
| |
| Abstract: | Electrochemical behavior of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones and 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-one was studied. Reductive dehalogenation of cyclohexa-2,5-dien-1-ones having a halogen atom at the neopentyl-like carbon atom gives the corresponding carbanion which undergoes anionic cyclopropyl-allyl rearrangement with subsequent addition of proton to form 3,4-dimethylphenol. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
