Highly enantioselective transfer hydrogenation of fluoroalkyl ketones |
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Authors: | Sterk Damjan Stephan Michel Mohar Barbara |
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Institution: | Laboratory of Organic and Medicinal Chemistry, National Institute of Chemistry, Hajdrihova 19, SI-1001 Ljubljana, Slovenia. |
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Abstract: | Structure: see text] The asymmetric transfer hydrogenation of fluoroalkyl ketones mediated by Ru(eta6-arene)((S,S)-R2NSO2DPEN)] catalysts using HCO2H-Et3N afforded the corresponding alcohols with high ee's and in excellent yields. |
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