On-line determination of bipyridylium herbicides in water by HPLC |
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Authors: | M Ibáñez Y Picó J Mañes |
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Institution: | (1) Laboratori de Bromatologia i Toxicologia, Facultat de Farmàcia, Universitat de València, Av. Vicent Andrés Estelles s/n, 46100 Burjassot, València, Spain |
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Abstract: | Summary Selective on-line solid phase extraction (SPE) and liquid chromatography determination (HPLC) of diquat, paraquat and difenzoquat
from environmental water samples has been accomplished with Graphitized Carbon Black (GCB) as both extraction and analytical
columns. The method involved passing of 50 mL of water through a cartridge filled with Carbograph. In the elution step, the
herbicides were transferred from the cartridge to the analytical column (Hypercarb) by mean of a gradient of pH 3 aqueous
solution of tetramethylammonium hydroxide (TMAOH) and ammonium sulphate and methanol. Hypercarb columns were found to give
a low probability of false positives for bypiridylium herbicides and are very selective for polar compounds. Recovery was
better than 80 %. The breakthrough volume was studied with distilled water spiked with the herbicides at various concentration
levels (from 0.1 to 20 μg L−1). The limits of quantification of the method were lower than 0.1 μg L−1. The total analytical method was applied to surface waters from Torreblanca Nature Park (Castelló, Spain).
Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996. |
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Keywords: | Column liquid chromatography Solid phase extraction Graphitized carbon black Diquat paraquat and difenzoquat |
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