Features of ion hydration and ion association in sub- and supercritical aqueous solutions of rubidium bromide |
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Authors: | M V Fedotova |
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Institution: | 1.Institute of Solution Chemistry,Russian Academy of Sciences,Ivanovo,Russia |
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Abstract: | Results of investigations by the integral equation method in the XRISM approximation of features of structure formation in
sub- and supercritical 0.5 M aqueous solution of RbBr. As the system passes from the sub- to supercritical state, the tetrahedral
network of the solvent is destroyed, which is typical of water and aqueous solutions; thermal dehydration of the cation and
anion are also observed. Dehydration is accompanied by contraction of the first hydration sphere of Rb+ and extension of the first hydration sphere of Br−. Both in sub- and supercritical solutions conditions a minor amount of contact ion pairs is present whose fraction is Higher
by 15% compared to that in standard conditions. |
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